Title of article
Chlorobis(pentafluorophenyl)alane: synthesis, crystal structure, and polymerization catalysis
Author/Authors
Debashis Chakraborty، نويسنده , , Eugene Y.-X. Chen، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
4
From page
698
To page
701
Abstract
Reaction of Al(C6F5)3 with 0.34 equiv CH2Cl2 cleanly produces chlorobis(pentafluorophenyl)alane (C6F5)2AlCl, the dimeric structure in the solid-state of which has been confirmed by X-ray diffraction studies. This chloroalane exhibits remarkable activity in polymerizations of styrene, ε-caprolactone, and cyclohexene oxide.
Keywords
Organoalane , Alane , Catalyst , Polymerization catalysis
Journal title
Inorganic Chemistry Communications
Serial Year
2002
Journal title
Inorganic Chemistry Communications
Record number
1315664
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