• Title of article

    An amino acid coordinated vanadium (IV) complex: Synthesis, structure, DFT calculations and VHPO mimicking catalytic bromoperoxidation of organic substrates

  • Author/Authors

    Urmila Saha، نويسنده , , Tapan Kr. Si، نويسنده , , Prasanta Kr. Nandi، نويسنده , , Kalyan K. Mukherjea، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2013
  • Pages
    4
  • From page
    43
  • To page
    46
  • Abstract
    A new VHPO mimicking oxovanadium(IV) complex [VO(sal-l-val)(phen)] (sal-l-val = Schiff base derived from salicylaldehyde and l-valine; phen = 1,10-phenanthroline) has been synthesized and characterized by elemental analysis, UV–vis, IR spectroscopy, ESI-MS, EPR and single crystal XRD studies. The structural and spectral parameters were further supported using DFT calculations. The complex was found to exhibit vanadium dependent haloperoxidase (VPHO) activity.
  • Keywords
    DFT calculations , Catalytic activity , Oxovanadium(IV) complex , Single crystal XRD , Haloperoxidase activity , Bromination of olefinic alcohols
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2013
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1315800

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1315800