Title of article
Synthesis, structure and magnetic properties of a 3D anionic framework based on butterfly Ni4 clusters
Author/Authors
Ying Zhao ، نويسنده , , Lu-Fang Ma، نويسنده , , Zhen-Zhen Shi، نويسنده , , Min-Le Han، نويسنده , , Li-Ya Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
4
From page
50
To page
53
Abstract
A 3D MOF {[Ni(H2O)6][Ni4L2(μ3-OH)2(H2O)2]}n (1) with a (4,8)-connected flu net is constructed by a butterfly-like tetranuclear [Ni4(μ3-OH)2(COO)8]2 − anionic cluster and organic linker 2,3′,5,5′-biphenyl tetracarboxylic acid (H4L). The disordered [Ni(H2O)6]2 + cations fill in the free voids of anionic framework in 1. Magnetic susceptibility measurements indicate that complex 1 shows weak antiferromagnetic interactions.
Keywords
NiII complex , 2 , 5?-Biphenyl tetracarboxylic acid , 5 , Magnetic properties , 3?
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1315802
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