Title of article
The first one-dimensional coordination polymer containing O–H⋯F–Ni hydrogen bonding: crystal structure of [Ni3(dpa)4F2][Ni3(dpa)4(H2O)2](BF4)2·2CH3OH
Author/Authors
Hui Li، نويسنده , , Gene-Hsiang Lee، نويسنده , , Shie-Ming Peng، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
1
To page
4
Abstract
The one-dimensional coordination polymer, [Ni3(dpa)4F2][Ni3(dpa)4(H2O)2](BF4)2·2CH3OH (dpa−=bis(2-pyridyl)amido ligand), has been constructed. The title complex crystallizes in the triclinic system, space group P1̄, with a=11.5966(1), b=19.5609(2), c=20.1509(2) Å, α=79.5672(4), β=75.4196(4), γ=76.2199(5)°, Z=2. The rare type hydrogen bonding of O–H⋯F–Ni links the two kinds of the trinickel metal string complexes as building blocks.
Keywords
Hydrogen bonding , Coordination polymer , Metal string complexes , Supramolecular chemistry
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1315898
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