Title of article
Facile C–N cleavage reactions of secondary and tertiary alkyl amines by P,O chelating rhodium and iridium complexes
Author/Authors
Yasuhiro Yamamoto، نويسنده , , Jouji Seta، نويسنده , , Hiroshi Murooka، نويسنده , , Xiaohong Han، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
202
To page
205
Abstract
The reactions of Cp*MCl(MDMPP-P,O) (1: M=Rh; 3: M=Ir; MDMPP-P,O=PPh2(C6H3-2-O-6-MeO)) with secondary or tertiary alkyl amine (R2NH or R3N) in the presence of KPF6 underwent a C–N cleavage of amine to afford primary amine complex [Cp*M(MDMPP-P,O) (RNH2)](PF6) (2: M=Rh; 4: M=Ir).
Keywords
Iridium , p , O chelating ligand , C–N cleavage , Rhodium
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1315943
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