• Title of article

    Some reactions of Cp*TiMe2(OAr) and Cp*TiMe(CF3SO3)(OAr) with 5-hexen-1-ol and 3-buten-1-ol, structural analysis for Cp*Ti(CF3SO3)[OCH2(CH2)3CHCH2](OAr) (OAr=O-2,6-iPr2C6H3)

  • Author/Authors

    Kotohiro Nomura، نويسنده , , Yumiko Hatanaka، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    6
  • From page
    517
  • To page
    522
  • Abstract
    Reaction of Cp*TiMe(CF3SO3)(OAr) (2, OAr=O-2,6-iPr2C6H3) with 5-hexen-1-ol in n-hexane gave Cp*Ti(CF3SO3)[OCH2(CH2)3CHCH2](OAr) (3) exclusively (94% yield). 3 was very stable upon heating, and the structural analysis has been made by X-ray crystallography. Reaction of Cp*TiMe2(OAr) with both 5-hexen-1-ol and 3-buten-1-ol have also been explored.
  • Keywords
    Titanium complex , Alken-1-ol , Half-titanocene , Olefin polymerization
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2003
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1316020

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1316020