Title of article
First two-dimensional framework material constructed from bicapped Keggin structure clusters: [Cu(en)2(H2O)]{[PMoVI8VIV6O42Cu(en)2][Cu0.5(en)]3} · 5.5H2O
Author/Authors
Cheng-Ling Pan، نويسنده , , Ji-Qing Xu*، نويسنده , , De-Qing Chu، نويسنده , , Guang-Hua Li، نويسنده , , Zheng-Liang Lü، نويسنده , , Guang-Di Yang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
3
From page
939
To page
941
Abstract
The hydrothermal reaction of CuCl2 · 2H2O, Na2MoO4 · 2H2O, NH4VO3, ethylenediamine (en) and H3PO4 yields a novel two-dimensional open-framework material. The extended structure consists of a network of {PMo8V6O42 [Cu(en)2]}5− cages, with each cage connected to three other neighboring units via [Cu(en)2]2+ bridging groups.
Keywords
Polyoxometalate , Cluster compound , Hydrothermal synthesis , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316121
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