Title of article
Structural characterization of ({[tren]Zn(HOMe)} · ClO4 · BPh4)(tren=tris(2-aminoethyl)amine) and CO2 fixation into monomethyl carbonato zinc(II) complex
Author/Authors
M.M. Ibrahim، نويسنده , , Kazuhiko Ichikawa، نويسنده , , Motoo Shiro، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
5
From page
1030
To page
1034
Abstract
The reaction of both tris(2-aminoethyl)amine and tris(2-dimethylaminoethyl)amine with Zn(ClO4)2 in the presence of equimolar amount of NaBPh4 in methanol afforded two different zinc(II) complexes, namely ({[tren]Zn(HOMe)} · ClO4 · BPh4) 1 and ({[trenMe6]Zn} · ClO4 · BPh4) 2. Zinc(II) Complex 1, which has been structurally characterized by X-ray crystallography, takes up CO2 in methanol in the presence of base to fix it into monomethyl carbonato complex ({[tren]Zn(OCO2Me)} · BPh4 · 2MeOH) 3.
Keywords
CO2 fixation , Zinc(II) complexes , X-ray crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2003
Journal title
Inorganic Chemistry Communications
Record number
1316142
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