• Title of article

    Reactions of [(η6-Me6C6)Ru(Ph2PCHCH2)Cl2] with 1-ethynylcycloalkanols leading to methoxy-alkenyl carbenes via vinylvinylidene and/or allenylidene intermediates

  • Author/Authors

    Kesete Y. Ghebreyessus، نويسنده , , John H. Nelson، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2003
  • Pages
    4
  • From page
    1044
  • To page
    1047
  • Abstract
    Methoxy-alkenyl carbenes 1 and 2 have been synthesized by treating a dichloro-methane/methanol solution of the [(η6-Me6C6)Ru(Ph2PCHCH2)Cl2] complex with an excess of 1-ethynyl-1-cyclohexanol and 1-ethynyl-1-cyclopentanol in the presence of NaPF6. The compounds were characterized by IR and 1H, 13C{1H}, 31P{1H} NMR spectroscopies and by elemental analyses. The crystal structure of 2 has also been determined by X-ray crystallography.
  • Keywords
    crystal structure , Ruthenium(II) complexes , Multinuclear NMR , Allenylidene , Vinylidene
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2003
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1316145

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1316145