Title of article
A half cleaved zirconacyclopentadiene
Author/Authors
Matthias Zeller، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
245
To page
248
Abstract
When the sterically strained bicyclic zirconacyclopentadiene 2 is reacted with two equivalents of iodine in the presence of copper(I) chloride, the diiodinated product 4 forms in the range of 10 h. However, when reacted only for 2 h, the monoiodinated zirconium complex 3 is isolated. 3 shows an unexpected stability towards hydrolysis and oxidation. The molecular structure of complex 3 has been determined by X-ray structural analysis.
Keywords
Zirconacyclopentadienes , Half Cleavage , Alkenylzirconocenes , Alkenyliodides
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316320
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