Title of article
The first examples of platinum(II)-amine complexes containing 1,2-dicarba-closo-dodecaborane(12)
Author/Authors
Jean A. Todd، نويسنده , , Louis M. Rendina، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
3
From page
289
To page
291
Abstract
Treatment of the labile precursor complexes cis- or trans-[PtCl(dmf)(NH3)2]OTf (dmf=N,N-dimethylformamide; OTf=trifluoromethanesulfonate) with the monodentate 1-aminoalkyl-1,2-carborane ligands NH2(CH2)nC2B10H11 (n=1,3) afforded the moderately-stable species cis- or trans-[PtCl(NH3)2{NH2(CH2)nC2B10H11}]OTf, respectively. The novel complexes are the first examples of platinum(II)-amine derivatives containing a 1,2-dicarba-closo-dodecaborane(12) (closo-1,2-carborane) ligand.
Keywords
closo-1 , Electrospray ionisation mass spectrometry , NMR spectroscopy , Platinum(II) complex , 2-Carborane
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316333
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