• Title of article

    Reversible π-coordination of triallylphosphine in a trinuclear ruthenium carbonyl cluster

  • Author/Authors

    Anders Thapper، نويسنده , , Emma Sparr، نويسنده , , Brian F.G. Johnson، نويسنده , , Jack Lewis، نويسنده , , Paul R. Raithby، نويسنده , , Ebbe Nordlander، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    4
  • From page
    443
  • To page
    446
  • Abstract
    The triallylphosphine-substituted clusters [Ru3(CO)11{P(CH2CHCH2)3}], [Ru3(CO)10{P(CH2CHCH2)3}2] and [Ru3(CO)10{σ;π-CH2CHCH2P(CH2CHCH2)2}] have been prepared; reaction of [Ru3(CO)10{σ;π-CH2CHCH2P(CH2CHCH2)2}] with phosphines/phosphites leads to cleavage of the Ru–allyl π-bond and formation of [Ru3(CO)11{P(CH2CHCH2)3}(PR3)].
  • Keywords
    hemilabile ligand , Cluster , Allylphosphine
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2004
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1316377

    • Link To Document
    https://search.isc.ac/dl/search/defaultta.aspx?DTC=10&DC=1316377