Title of article
A novel polymeric copper strain formed by helically terpyridyl-surrounded Cu22+ units
Author/Authors
Mohammed Al-Anber، نويسنده , , Bernhard Walfort، نويسنده , , S. Vatsadze، نويسنده , , Heinrich Lang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
799
To page
802
Abstract
Terpyridine (terpy) (2) reacts with a 1:1 mixture of [{[Ti](μ−σ, π-CCSiMe3)2}Cu(NCMe)]PF6 (1) and [{[Ti](μ−σ,π-CCSiMe3)2}CuO2NO (4) ([Ti](η5-C5H4SiMe3)2Ti) to produce the polymeric copper strain {[Cu2(terpy)2]PF6, NO3}n (6) in which dimeric [Cu2(terpy)2]2+ units are linked by copper–copper interactions; a possible reaction mechanism is presented.
Keywords
Copper–copper interaction , Coordination polymer , Titanium , copper , Terpyridyl
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316475
Link To Document