• Title of article

    A novel polymeric copper strain formed by helically terpyridyl-surrounded Cu22+ units

  • Author/Authors

    Mohammed Al-Anber، نويسنده , , Bernhard Walfort، نويسنده , , S. Vatsadze، نويسنده , , Heinrich Lang، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2004
  • Pages
    4
  • From page
    799
  • To page
    802
  • Abstract
    Terpyridine (terpy) (2) reacts with a 1:1 mixture of [{[Ti](μ−σ, π-CCSiMe3)2}Cu(NCMe)]PF6 (1) and [{[Ti](μ−σ,π-CCSiMe3)2}CuO2NO (4) ([Ti](η5-C5H4SiMe3)2Ti) to produce the polymeric copper strain {[Cu2(terpy)2]PF6, NO3}n (6) in which dimeric [Cu2(terpy)2]2+ units are linked by copper–copper interactions; a possible reaction mechanism is presented.
  • Keywords
    Copper–copper interaction , Coordination polymer , Titanium , copper , Terpyridyl
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2004
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1316475