Title of article
Synthesis and structure of bis{η5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-κS)cyclopentadienyl}titanium(IV)
Author/Authors
Jiri Pinkas، نويسنده , , R?bert Gyepes، نويسنده , , Petr ?t?pni?ka، نويسنده , , Ji??? Kubi?ta، نويسنده , , Michal Hor??ek، نويسنده , , Karel Mach، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2004
Pages
4
From page
1135
To page
1138
Abstract
Bis{η5-(N,N-dimethylaminodimethylsilyl)tetramethylcyclopentadienyl}dichlorotitanium(IV), [TiCl2{η5-C5Me4(SiMe2NMe2)}2] (1), reacts with sulfane under cleavage of both Si–N and Ti–Cl bonds to give sulfido-tethered titanocene compound bis{η5-1,2,3,4-tetramethyl-5-(dimethylsilylsulfido-κS)cyclopentadienyl}titanium(IV), [Ti{η5-C5Me4(SiMe2S- κS)}2] (4), and dimethylamine hydrochloride as the byproduct. The crystal structure of compound 4 has been determined by single-crystal X-ray diffraction.
Keywords
titanocene , Pendant amine group , Cyclopentadienylsulfide bridge , Sulfanolysis , crystal structure , Titanium
Journal title
Inorganic Chemistry Communications
Serial Year
2004
Journal title
Inorganic Chemistry Communications
Record number
1316563
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