Title of article
Preparation and characterization of carboximidate iron(II) complexes
Author/Authors
Liyi Chen، نويسنده , , Wen Zhang، نويسنده , , Shuping Huang and Xinjian Kou، نويسنده , , Xianglin Jin، نويسنده , , Wenhua Sun، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
3
From page
41
To page
43
Abstract
The reactions of C5H4NCHdouble bond; length as m-dashNNHC(double bond; length as m-dashO)Ph (1) with Fe(II) chloride gave [Fe2(C5H4NC(OEt)double bond; length as m-dashNNHC(double bond; length as m-dashO)Ph)2(μ-OEt)2Cl2]) (2) in ethanol and [Fe2(C5H4NC(OMe)double bond; length as m-dashNNHC(double bond; length as m-dashO)Ph)2(μ-OMe)2Cl2] (3) in methanol as well as [Fe(C5H4NCHdouble bond; length as m-dashNNHC(double bond; length as m-dashO)Ph)Cl2] (4) in tetrahydrofuran, respectively. The X-ray diffraction analysis reveals their structures and complex 4 is proposed as an intermediate of formation of complexes 2 and 3.
Keywords
Carboximidate , Fe(II) complex , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316619
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