Title of article
The interaction of nickelocene with 3,6-di-tert-butyl-o-benzoquinone
Author/Authors
A.V. Piskunov، نويسنده , , G.K. Fukin، نويسنده , , Yu.A. Kurskii، نويسنده , , V.K. Cherkasov، نويسنده , , G.A. Abakumov، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
339
To page
342
Abstract
The interaction of nickelocene with 3,6-di-tert-butyl-o-benzoquinone in toluene gives new 18-electron complex (η5-cyclopentadienyl)(η3-{5,8-di-tert-butyl-3a,9a-dihydro-1H-cyclopenta(b)[1,4]benzodioxin-1-il})nickel(II) as the main product of hetero-Diels–Alder reaction. This process being carried out in THF solution is accompanied by ligands exchange and leads mainly to octahedral complex bis(3,6-di-tert-butyl-o-benzosemiquinonate)-bis(tetrahydrofuran)nickel(II).
Keywords
o-Semiquinone , X-ray diffraction , Nickelocene , o-quinone , ?-Allyl complex
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316697
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