Title of article
A novel copper (II) metallacycle as a building block for the assembly of an extended supramolecular array containing channels and helical chains
Author/Authors
Geoffrey J.T. Cooper، نويسنده , , De-Liang Long، نويسنده , , Leroy Cronin، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
3
From page
737
To page
739
Abstract
Complexation of copper (II) perchlorate with cis,cis-1,3,5-cyclohexanetricarboxylic acid (CTA) and cis,trans-1,3,5-triaminocyclohexane (trans-tach) in the presence of triethylamine leads to the formation of a dinuclear metallacycle; [Cu2(trans-tach)2 (CTA)2] · 14H2O (1). The crystal structure of 1 shows an extended hydrogen bonded network comprising linear chains of metallacycles running perpendicular to solvent occupied channels.
Keywords
Supramolecular , Coordination chemistry , Hydrogen bonding , Metallacycles , Rigid aliphatic ligands , Metal organic frameworks , Self assembly
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316794
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