Title of article
Dicarboxylic acid esters from the carbonylation of unsaturated esters under mild conditions
Author/Authors
Cristina Jiménez-Rodriguez، نويسنده , , Graham R. Eastham، نويسنده , , David J. Cole-Hamilton، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
878
To page
881
Abstract
The methoxycarbonylation of unsaturated acids or esters catalysed by Pd complexes of bis(ditertiarybutyl-phosphinomethyl)benzene (DTBPMB) produces α,ω-diesters with selectivities >95%, even if the double bond is deep in the chain or conjugated to the carbonyl group; unsymmetrical esters can also be produced with high selectivity.
Keywords
?-Diesters , Acrylic acids , Phosphine , Palladium , methoxycarbonylation , ?
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316830
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