Title of article
Ni(II), Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol: Formation of coordinated phenoxyl radical
Author/Authors
Anastasiya V. Yakovenko، نويسنده , , Sergey V. Kolotilov، نويسنده , , Anthony W. Addison، نويسنده , , Swiatoslaw Trofimenko، نويسنده , , Glenn P.A. Yap، نويسنده , , Victoria Lopushanskaya، نويسنده , , Vitaly V. Pavlishchuk، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2005
Pages
4
From page
932
To page
935
Abstract
Ni(II), Co(II) and Mn(II) tris(pyrazolyl)borate complexes with 2,6-di-tert-butyl-4-carboxy-phenol were synthesized and characterized crystallographically (Ni and Co complexes), spectroscopically and electrochemically. It was found that oxidation of Ni and Co complexes resulted in the formation of coordinated phenoxyl radical and diphenoquinone, whereas only quinone formed in the case of Mn complex and free 2,6-di-tert-butyl-4-carboxy-phenol.
Keywords
Redox properties , 3d-Metals , Tris(pyrazolyl)borates , X-ray structure , ESR spectra , Phenoxyl radical
Journal title
Inorganic Chemistry Communications
Serial Year
2005
Journal title
Inorganic Chemistry Communications
Record number
1316844
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