Title of article
Hydrothermal synthesis, characterization and properties of bi-capping pseudo-Keggin type tungstovanadophosphate compound:
Author/Authors
Yan Xu، نويسنده , , Linbo Nie، نويسنده , , Guangning Zhang، نويسنده , , Qi Chen، نويسنده , , Xuefang Zheng، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
3
From page
329
To page
331
Abstract
A novel polyoxometalate image (1) has been synthesized under hydrothermal conditions. The X-ray crystallography shows that 1 contains a novel bi-capping pseudo-Keggin type heteropolyanion image and a four-nuclei cation [Co4(HPO3)2(C12H8N2)8(H2O)2]4+. The different heteropolyanions are linked by water molecules and the cations [Co4(HPO3)2(C12H8N2)8(H2O)2]4+ through the hydrogen bonds, to form an extensive three-dimensional supramolecular assembly.
Keywords
Metal–oxygen cluster , structure , Heteropolyanion , Single crystal , Hydrothermal synthesis
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1316987
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