Title of article
Tridentate facial coordination mode of an unsymmetrical tetradentate diazine ligand in an iron(III) complex
Author/Authors
Subramanya Gupta Sreerama، نويسنده , , Abhik Mukhopadhyay، نويسنده , , Samudranil Pal ، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
1083
To page
1086
Abstract
Synthesis, structure and properties of a distorted octahedral iron(III) complex, [Fe(salpahn)2]ClO4 (Hsalpahn = 2-(pyridin-2-ylmethylene-hydrazonomethyl)-phenol), are described. The X-ray structure reveals the facial disposition of pyridine-N, imine-N and phenolate-O donor salpahn− with the formation of two six-membered chelate rings. The self-assembly pattern via intermolecular hydrogen bonds in the crystal lattice is reported.
Keywords
Iron(III) complex , Diazine ligand , crystal structure , Facial coordination , Self-assembly
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317178
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