Title of article
The first metal complex with the hydrazine dicarboxylate dianion: Na2(O2CNHNHCO2)(H2O)3
Author/Authors
Krishnan Srinivasan، نويسنده , , Subbaiah Govindarajan، نويسنده , , William T.A. Harrison، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2006
Pages
4
From page
1117
To page
1120
Abstract
The title compound is the first complex of a metal ion with the hydrazinedicarboxylate dianion. One of the sodium cations is coordinated by two N,O-bidenate and two O-monodentate ligands to result in distorted trans-NaN2O4 octahedra. Crystal data: Na2(O2CNHNHCO2) · 3H2O, Mr = 218.08, triclinic, image (No. 2), a = 5.5123 (2) Å, b = 8.7311 (3) Å, c = 8.8117 (3) Å, α = 107.005 (2)°, β = 99.431 (2)°, γ = 101.552 (2)°, V = 385.98 (2) Å3, Z = 2, R(F) = 0.027, wR(F2) = 0.092.
Keywords
Ligand , Sodium , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2006
Journal title
Inorganic Chemistry Communications
Record number
1317187
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