Title of article
First X-ray crystal structure of cation [cis-Co(en)2(H2O)Cl]2+: Synthesis, spectroscopic and X-ray structural study of [cis-Co(en)2(H2O)Cl](C6H5SO3)2·H2O
Author/Authors
Rajni Sharma، نويسنده , , Raj Pal Sharma*، نويسنده , , Konstantin Karaghiosoff، نويسنده , , Thomas M. Klapoetke، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
4
From page
139
To page
142
Abstract
A new cobalt(III) complex salt, [cis-Co(en)2(H2O)Cl](C6H5SO3)2 · H2O] (I) has been synthesized and characterized by single crystal X-ray structure determination and NMR spectroscopy. This is a first report of the cobalt(III) cation in cis-configuration. The crystal lattice of the complex salt is stabilized by electrostatic forces of attraction and hydrogen bonding interactions.
Keywords
UV/visible spectroscopy , Cobalt(III) , Coordination chemistry , Benzenesulphonate , X-ray crystallography , IR spectroscopy
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317272
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