Title of article
Copper(II) complexes with chiral reduced Schiff bases: Helical self-assembly via intermolecular C–H⋯O interactions
Author/Authors
Vamsee Krishna Muppidi، نويسنده , , Sunirban Das، نويسنده , , Pallepogu Raghavaiah، نويسنده , , Samudranil Pal ، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
5
From page
234
To page
238
Abstract
Copper(II) complexes having the general formula [Cu(Ln)2] with the N,O-donor reduced Schiff bases N-(2-hydroxy-5-X-benzyl)-(R)-α-methylbenzylamine and N-(2-hydroxy-5-X-benzyl)-(S)-α-methylbenzylamine (X = Cl and Br) (HLn) are described. These chiral complexes crystallize in the noncentrosymmetric P212121 (X = Cl) and P21 (X = Br) space groups. In each case, self-assembly via intermolecular C–H⋯O interaction leads to a supramolecular helical superstructure.
Keywords
Copper(II) complexes , crystal structures , Reduced schiff bases , Helical self-assembly , Chiral
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317296
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