Title of article
A novel bismuth ion-bridged chainlike assembly from paradodecatungstate [H2W12O42]10− anions: (NH4)7[Bi(H2W12O42)] · 20H2O
Author/Authors
Zhen-He Xu، نويسنده , , Xinlong Wang ، نويسنده , , Yangguang Li، نويسنده , , En-Bo Wang، نويسنده , , Chao Qin، نويسنده , , Yan-Ling Si، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
3
From page
276
To page
278
Abstract
A new polyoxotungstate (NH4)7[Bi(H2W12O42)] · 20H2O has been synthesized in aqueous solution and characterized by elemental analysis, IR spectroscopy, TG analysis and single-crystal X-ray diffraction. The most interesting structural feature of 1 is that the paradodecatungstate [H2W12O42]10− anions are linked, for the first time, by the trivalent main group atom BiIII which appeared commonly as a heteroatom in polyoxometalate chemistry, into a one-dimensional chainlike structure.
Keywords
Polyoxometalates , crystal structure , Tungstate , Bismuth
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317306
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