Title of article
A new hydrogen-bonded charge-transfer complex [Ni(Hpydt)2]TNAP: Synthesis, structure and electrical conductivity
Author/Authors
Sota Shibahara، نويسنده , , Hiroshi Kitagawa، نويسنده , , Takashi Kubo، نويسنده , , Kazuhiro Nakasuji، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
3
From page
860
To page
862
Abstract
Bis(2,3-pyridinedithiolate)nickel(II) complex gives a hydrogen-bonded charge-transfer (HBCT) complex with 11,11,12,12-tetracyanonaphtho-2,6-quinodimethane (TNAP), [Ni(Hpydt)2]TNAP. This is the first example of an HBCT complex composed of TNAP. The donor and acceptor components alternate within each stack. The ionicity of the each component is estimated to be ±1.0. The electrical resistivity of the complex at 298 K is 640 Ω cm and the activation energy of 137 meV.
Keywords
Electrical conductivity , Semiconductors , Band calculation , Hydrogen-bonded charge-transfer complex , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317439
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