Title of article
The synthesis, reactivity and 1H NMR investigation of the hydroxyborohydride anion
Author/Authors
Tomasz Ruman، نويسنده , , Anna Ku?nierz، نويسنده , , Agata Jurkiewicz، نويسنده , , Andrzej Le?، نويسنده , , Wojciech Rode، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2007
Pages
5
From page
1074
To page
1078
Abstract
Hydroxyborohydride (sodium and potassium salts) were prepared by a one-pot method and the 1H NMR spectrum of sodium hydroxyborohydride was recorded for the first time. Based on an NMR experiment, hydroxyborohydride was found to be more reactive toward acetone carbonyl than borohydride. The calculated 11B- and 10B–H coupling constants are in very good agreement with experimental data, and support the hypothesis about the detection of the (BH3OH)− anion as an individual species in solution.
Keywords
1H NMR , Boron , Carbonyl compounds , Reduction , Hydroxyborohydride
Journal title
Inorganic Chemistry Communications
Serial Year
2007
Journal title
Inorganic Chemistry Communications
Record number
1317493
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