Title of article
A new [As3Mo3O15]3− fragment decorated with Cu(I)-imi (imi = imidazole) complexes: Synthesis, structure and electrochemical properties
Author/Authors
Zhifeng Zhao، نويسنده , , Baibin Zhou، نويسنده , , Zhanhua Su، نويسنده , , Huiyuan Ma، نويسنده , , Chunxiang Li، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
648
To page
651
Abstract
A novel molybdenum arsenate compound [{Cu(imi)2}3As3Mo3O15] · H2O (imi = imidazole) 1, has been prepared by hydrothermal method and structurally characterized by elemental analysis, IR, XPS, TG analysis and single-crystal X-ray diffraction analysis. Compound 1 represents the first example of molybdenum arsenate fragment [As3Mo3O15]3− as polydentate ligand covalently bonded to three image complexes through Ob⋯Ot⋯Ob (Ot, terminal oxygen; Ob, bridging oxygen) atoms. The electrochemical behavior and electrocatalysis of 1-modified carbon paste electrode (CPE) have been studied in detail.
Keywords
Molybdenum arsenate , Copper-complex , Electrochemical properties
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317766
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