Title of article
In situ hydrothermal decarboxylation for unprecedented three-dimensional lanthanide–organic frameworks
Author/Authors
Cai-Ming Liu، نويسنده , , Deqing Zhang، نويسنده , , Daoben Zhu، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
4
From page
903
To page
906
Abstract
In situ hydrothermal decarboxylation was observed during preparing two novel three-dimensional (3D) lanthanide–organic frameworks Ln(2,5-PyDC)(3-PyC)(H2O) (Ln = Nd, Sm; 2,5-H2PyDC = 2,5-pyridinedicarboxylic acid, 3-HPyC = 3-pyridinecarboxylic acid). X-ray crystallographic analyses revealed that both complexes are isomorphous and show an interesting topology. Magnetic study indicated the coupling interaction between Ln3+ ions in both complexes is weak.
Keywords
Hydrothermal in situ ligand reaction , Magnetic property , Lanthanide–organic framework , crystal structure , Coordination polymer
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317838
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