Title of article
A novel microporous hydrogen-bonding framework constructed with tetrathiafulvalene tetracarboxylate ligand: Synthesis, structure and magnetic properties
Author/Authors
Yin-Feng Han، نويسنده , , Min Li، نويسنده , , Tianwei Wang، نويسنده , , Yi-Zhi Li، نويسنده , , Zhen Shen، نويسنده , , You Song، نويسنده , , Xiao-Zeng You، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
945
To page
947
Abstract
A novel microporous complex [Co2(μ2-OH2)2(H2O)8][H2(TC-TTF)]2 · 2H2O [H4(TC-TTF) = tetra(carboxyl)tetrathiafulvalene] was self-assembled from H4(TC-TTF) and CoCl2 · 6H2O. The complex forms a 3D supramolecular network through hydrogen-bonding and S···S interactions and shows an 1D microporous open channel along the a axis (3.5 × 4.7 Å). Variable-temperature magnetic susceptibility measurement at 1.8–300 K reveals weak ferromagnetic coupling between CoII ions.
Keywords
Cobalt (II) complex , Magnetic properties , H4(TC-TTF) , hydrogen bonds
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317849
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