Title of article
A new polymorph of 4′-tolyl-2,2′:6′,2′′-terpyridine (ttpy) and the single crystal structures of [Fe(ttpy)2][PF6]2 and [Ru(ttpy)2][PF6]2
Author/Authors
Jonathon E. Beves، نويسنده , , Paulina Chwalisz، نويسنده , , Edwin C. Constable، نويسنده , , Catherine E. Housecroft، نويسنده , , Markus Neuburger، نويسنده , , Silvia Schaffner، نويسنده , , Jennifer A. Zampese، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
1009
To page
1011
Abstract
Single crystals of a new polymorph of 4′-tolyl-2,2′:6′,2′′-terpyridine (ttpy) have been grown by evaporation of a hexane–ethyl acetate solution of the ligand; the packing features weak π-stacking and Npyridine···HC interactions between stacks of ttpy molecules. Improved syntheses of [M(ttpy)2][PF6]2 (M = Fe, Ru), and the single crystal structures of [Fe(ttpy)2][PF6]2 · 2.2MeCN and [Ru(ttpy)2][PF6]2 · 1.75MeCN · 0.2H2O are reported.
Keywords
4?-Tolyl-2 , 2?:6? , 2??-terpyridine , Coordination , Polymorph , Ruthenium , Iron
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317868
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