Title of article
Synthesis, crystal structure and spectroscopic properties of a new chiral cadmium (II) malate
Author/Authors
Adel Beghidja، نويسنده , , Chahrazed Beghidja، نويسنده , , Guillaume Rogez، نويسنده , , Pierre Rabu، نويسنده , , Richard Welter، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
1088
To page
1090
Abstract
A new chiral 3D metal-organic coordination polymer [Cd((S)-mal)] (mal = malic acid), has been solvothermally synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. Colorless crystals crystallize in the orthorhombic system, space group P212121, a = 6.804(1), b = 8.488(2), c = 9.997(3) Å, V = 577.35 (2) Å3, Z = 4 and R1 = 0.0298. The structure of the compound exhibits a chiral 3D covalent framework based on chiral bridging ligands, the coordination environment around the CdII is pentagonal bipyramidal.
Keywords
Coordination polymer , Malate ligands , Chirality , cadmium , Hydrothermal synthesis
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317891
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