• Title of article

    The first polymeric thiogallate with lanthanide-containing counter cation, [Dy2(en)6(μ2-OH)2]Ga4S8

  • Author/Authors

    Chunying Li، نويسنده , , Jian Zhou، نويسنده , , Guo-Qing Bian، نويسنده , , Minghui Zhang، نويسنده , , Jie Dai، نويسنده ,

  • Issue Information
    روزنامه با شماره پیاپی سال 2008
  • Pages
    3
  • From page
    1327
  • To page
    1329
  • Abstract
    The title compound, [Dy2(en)6(μ2-OH)2]Ga4S8 (en = ethylenediamine), contains 1D infinite sinusoidal image anions and hydroxy bridged dinuclear dysprosium complex cations. Two bridging hydroxy ions connect two inversion-related Dy3+ ions to form a centrosymmetric dimer, in which a Dy2O2 rhomboidal core is formed. The title compound is the only example of the thiogallates with lanthanide-containing counter cation.
  • Keywords
    Thiogallate , lanthanide complex , Solvothermal synthesis , crystal structure
  • Journal title
    Inorganic Chemistry Communications
  • Serial Year
    2008
  • Journal title
    Inorganic Chemistry Communications
  • Record number

    1317958