Title of article
The first polymeric thiogallate with lanthanide-containing counter cation, [Dy2(en)6(μ2-OH)2]Ga4S8
Author/Authors
Chunying Li، نويسنده , , Jian Zhou، نويسنده , , Guo-Qing Bian، نويسنده , , Minghui Zhang، نويسنده , , Jie Dai، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2008
Pages
3
From page
1327
To page
1329
Abstract
The title compound, [Dy2(en)6(μ2-OH)2]Ga4S8 (en = ethylenediamine), contains 1D infinite sinusoidal image anions and hydroxy bridged dinuclear dysprosium complex cations. Two bridging hydroxy ions connect two inversion-related Dy3+ ions to form a centrosymmetric dimer, in which a Dy2O2 rhomboidal core is formed. The title compound is the only example of the thiogallates with lanthanide-containing counter cation.
Keywords
Thiogallate , lanthanide complex , Solvothermal synthesis , crystal structure
Journal title
Inorganic Chemistry Communications
Serial Year
2008
Journal title
Inorganic Chemistry Communications
Record number
1317958
Link To Document