Title of article
A new synthetic route towards a Ru(III) substituted heteropolytungstate anion
Author/Authors
Claire Besson، نويسنده , , Su Wen Chen، نويسنده , , Richard Villanneau، نويسنده , , Guillaume Izzet، نويسنده , , Anna Proust، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2009
Pages
3
From page
1042
To page
1044
Abstract
Microwave irradiation of a mixture of K7[PW11O39]·14H2O and [Ru(dmf)6](CF3SO3)3 allowed the straightforward hydrothermal synthesis of the Keggin-type [PW11O39RuIII(OH2)]4− anion. Physical characterizations of the corresponding tetrabutylammonium (TBA) salt are herein described. This study provides a complete set of spectroscopic and electrochemical references for RuIII-incorporating heteropolytungstates.
Keywords
XANES , Microwave activation , Ruthenium , Polyoxometalates , EPR spectroscopy
Journal title
Inorganic Chemistry Communications
Serial Year
2009
Journal title
Inorganic Chemistry Communications
Record number
1318269
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