Title of article
Macrocyclic hexanuclear zirconium(IV) complex bearing a bisaryloxyl N-heterocyclic-carbene ligand: Synthesis, structure, and catalytic properties
Author/Authors
Dao Zhang، نويسنده , , Gongwo GengShi، نويسنده , , Jinyang Wang، نويسنده , , Qin Yue، نويسنده , , Wenjun Zheng، نويسنده , , Linhong Weng، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
433
To page
435
Abstract
A rare macrocyclic hexazirconium(IV) complex with bisaryloxyl N-heterocyclic carbene ligand {(L)Zr(OSiMe3)(k2-[N^O])}6 (2) (image H[N^O]=image) was prepared from a mononuclear complex [(L)ZrCl2(THF)] (1). Complex 2 was structurally characterized and shows higher catalytic ethylene polymerization activities in the presence of methylaluminoxane (MAO).
Keywords
Zirconium , N-heterocyclic carbene ligands , ethylene polymerization , Multinuclear complex , Aryloxyl
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318435
Link To Document