Title of article
C,N-chelated dicyclopentadienylzirconium complexes and their possible use as hydrogenation catalysts
Author/Authors
Josef Bare?، نويسنده , , Zde?ka Pad?lkov?، نويسنده , , Philippe Meunier، نويسنده , , Nadine Pirio، نويسنده , , Didier Poinsot، نويسنده , , Ale? R??i?ka، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2010
Pages
3
From page
1512
To page
1514
Abstract
In situ generated Cp2Zr(n-Bu)Cl (6) reacts with {2-[(CH3)2NCH2]C6H4}2Pb to form exclusively {2-[(CH3)2NCH2]C6H4}Cp2ZrCl (7), [(CH3)2NCH2]C6H5, butene and elemental lead. The further derivatization of chloride (7) to fluoride (8), hydride (9), methyl derivative (10), and a reduction of 7 are also described. The crystal structures of 7–10 were determined. The catalytic activity of 9 and 10 in hydrogenation of styrene was also preliminarily tested.
Keywords
zirconocene , C , Hydrogenation , Transmetallation , N-chelating ligand
Journal title
Inorganic Chemistry Communications
Serial Year
2010
Journal title
Inorganic Chemistry Communications
Record number
1318711
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