Title of article
Self-assembly of cyclometallated Pd(II) compounds directed by C–H⋅⋅⋅π interactions: A structural evidence for metalloaromaticity in a cyclopalladated ring
Author/Authors
Anderson M. Santana، نويسنده , , Jana?na G. Ferreira، نويسنده , , Antonio C. Moro، نويسنده , , Sahra C. Lemos، نويسنده , , Antonio E. Mauro، نويسنده , , Adelino V.G. Netto، نويسنده , , Regina C.G. Frem، نويسنده , , Regina H.A. Santos، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
83
To page
86
Abstract
Structural studies on the two binuclear cyclometallated compounds [Pd(C2,N-bzan)(μ-N3)]2 (1) and [Pd(C2,N-bzan)(μ-Pz)]2 (2) (bzan = N-benzylideneaniline) have been carried out in this work. In both compounds, C–H⋅⋅⋅π interactions play an important role in the molecular self-assembly. In complex 1, ortho-CH bonds from bzan moiety interact with the cyclopalladated ring at a distance of Cbzan⋅⋅⋅Cg 3.448(6) Å, providing a new structural evidence for the metalloaromaticity of the cyclometallated ring.
Keywords
Metalloaromaticity , C–H???? interactions , Supramolecular chemistry , Cyclopalladated
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1318751
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