Title of article
Photochemical dehalogenation mediated by macrocyclic nickel(II) complexes
Author/Authors
Katsura Mochizuki، نويسنده , , Mana Suzuki، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
902
To page
905
Abstract
A new photochemical dehalogenation system mediated by macrocyclic nickel(II) complexes was developed. Using this system, which consists of a macrocyclic nickel(II) complex catalyst, triethanolamine (TEOA) as a sacrificial reductant, and the ruthenium complex [Ru(bpy)3](ClO4)2 as a photosensitizer, catalytic debromination of 1-bromo-4-t-butylbenzene in acetonitrile was effectively carried out. The catalytic capabilities of various macrocyclic nickel(II) complexes in debromination reactions were also elucidated.
Keywords
Macrocyclic ligands , Debromination , Catalytic reactions , Photochemical dehalogenation , Nickel(II) complexes
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1318951
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