Title of article
A novel Cu5II cluster-based 3D magnetic framework with an overall S = 1/2 spin ground state
Author/Authors
Zhongyi Liu، نويسنده , , Jing Chu، نويسنده , , Bo Ding، نويسنده , , Xiao-Jun Zhao، نويسنده , , En-Cui Yang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
925
To page
928
Abstract
A 3D (3,8)-connected tfz-d framework with unusual Cu5II clusters periodically extended by 5-nitroisophthalate (nip2−) ligands, {[Cu5(μ3-OH)2(μ2-H2O)2(H2O)4(nip)4]·5H2O}n (1), was hydrothermally synthesized and structurally characterized. Magnetically, the spin frustration in a vertex-sharing triangular aligned Cu5II cluster leads essentially to an overall S = 1/2 spin ground state of 1.
Keywords
Metal-cluster based coordination polymer , Pentanuclear CuII cluster , Magnetism
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1318957
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