Title of article
The formation of tetrameric oxotechnetium(V) and oxorhenium(V) complexes by cyclisation of a potentially multidentate thiocarbohydrazide derivative
Author/Authors
Dirk Hauenstein، نويسنده , , Ulrich Abram، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
4
From page
1262
To page
1265
Abstract
Tetrameric complexes of the composition [MO(L1)]4 (M = Tc, Re), where (L1)3– represents an asymmetric, trianionic cyclisation product with thiocarbamoylbenzamidinato and mercaptotriazolato donor sites, were formed during reactions of [TcOCl4]– or [ReOCl4]– with a potentially multidentate ligand derived from thiocarbohydrazide and N-[Nʹ,Nʹ-diethylamino(thiocarbonyl)]benzimidoyl chloride.
Keywords
Technetium , Oxo complex , Cyclisation , X-ray structure , Rhenium
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1319039
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