Title of article
A novel cationic dinuclear ruthenium complex: Synthesis, characterization and catalytic activity in the transfer hydrogenation of ketones
Author/Authors
Lei Wang، نويسنده , , Qin Yang، نويسنده , , Hua Chen، نويسنده , , Ruixiang Li، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2011
Pages
5
From page
1884
To page
1888
Abstract
A novel cationic dinuclear ruthenium complex [RuCl(HL)(TFTPP)]2 (H2L = 2,6-bis(5-phenyl-1H-pyrazol-3-yl)pyridine; TFTPP = tri(p-trifluoromethylphenyl)phosphine) has been synthesized and characterized by 31P{1H} NMR, 1H NMR, elemental analysis and X-ray crystallography. This complex is the first cationic dinuclear ruthenium complex bearing N4 ligand characterized by single crystal X-ray analysis. It exhibits good catalytic activity for the transfer hydrogenation of ketones in refluxing 2-propanol.
Keywords
Ruthenium , Dinuclear complex , N4 ligand , Ketone , Transfer hydrogenation
Journal title
Inorganic Chemistry Communications
Serial Year
2011
Journal title
Inorganic Chemistry Communications
Record number
1319184
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