Title of article
A thermally reversible photoinduced magnetic trinuclear complex [Cu2(bpmen)2][MoIV(CN)8]∙8H2O
Author/Authors
Haitao Xu، نويسنده , , Osamu Sato، نويسنده , , Zhihua Li، نويسنده , , Jianping Ma، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
3
From page
311
To page
313
Abstract
A trinuclear complex [CuII2(bpmen)2][MoIV(CN)8]∙8H2O was synthesized and structurally characterized, crystallized in the monoclinic system, space group Cc with cell constants a = 11.726(2)Å, b = 17.158(3)Å, c = 23.891(5)Å, β = 97.96(3)° and Z = 4. It exhibited thermally reversible photo-responsive properties on UV light irradiation through a MoIV to CuII charge transfer, which is potential interest for the molecular storage of information as a multifunctional molecule-based material.
Keywords
Charge transfer , crystal structure , Trinuclear complex , Molecule-based materials , Photomagnetic property
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319284
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