Title of article
Unusual heterometallic ZnMg(COO)3 building blocks for the construction of a homochiral srs-type metal-organic framework
Author/Authors
Hui Yang، نويسنده , , Tie-hu Li، نويسنده , , Fei Wang، نويسنده , , Jian Zhang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
3
From page
86
To page
88
Abstract
A new homochiral metal-organic framework [ZnMg(btc)(H2O)4](NO3) (1, btc = 1,3,5-benzenetricarboxylate) with unusual 3-connected heterometallic ZnMg(COO)3 building blocks has been solvothermally synthesized and structurally characterized with the aid of single crystal X-ray diffraction. Compound 1 crystallizes in a chiral space group and exhibits 3-connected srs structural topology. The results reveal the first srs-type metal-organic framework constructed from heterometallic building blocks.
Keywords
Chiral , Metal-organic framework , zinc , crystal structure , topology
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319309
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