Title of article
P–C bond cleavage in dppm derivatives: X-ray structure of [Pd2(μ2-P,C-PPh2CHPOPh2)(μ2-dppm)Cl(PPh2Me)]
Author/Authors
Susana Miranda، نويسنده , , Elena Cerrada، نويسنده , , Ar?nzazu Mend?a، نويسنده , , Prithwiraj Byabartta and Mariano Laguna ، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
151
To page
154
Abstract
cis-[PdCl2(dppm)] [dppm = 1,2-bis(diphenylphosphino)methane] reacts with NaOH in ethanol to afford [Pd2(μ2-P,C-PPh2CHPOPh2)(μ2-dppm)Cl(PPh2Me)], which clearly shows different aspects of the formation of PPh2Me from the starting dppm ligand, especially the μ2-P,C methanide coordination. The Pd–Pd bond length of 2.6754(4) Å is in the usual range for dipalladium(I) compounds.
Keywords
1 , 2-bis(diphenylphosphino)methane , dppm , Methanide , Palladium , P–C bond cleavage
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319519
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