Title of article
A hybrid compound based on porous metal–organic frameworks and polyoxometalates: NO adsorption and decomposition
Author/Authors
Feng-Ji Ma، نويسنده , , Shu-Xia Liu، نويسنده , , Guojian Ren، نويسنده , , Da-Dong Liang، نويسنده , , Sha Sha، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2012
Pages
4
From page
174
To page
177
Abstract
A new hybrid compound based on porous metal–organic frameworks and polyoxometalates H4[(Cu4Cl)3(BTC)8]2[SiW12O40]·(C4H12N)6·3H2O (NENU-15, BTC = 1, 3, 5-benzenetricarboxylate) has been hydrothermally synthesized and its crystal structure, stability and porosity have been characterized. The experimental results showed that the introduction of polyoxometalates improved the integral stability of the compound. In addition, NENU-15 was employed in NO removal for the first time. By virtue of the synergistic effect between host frameworks and guest polyoxometalates, it not only displayed good adsorption behavior for NO, but also exhibited superior activity in NO decomposition.
Keywords
Decomposition , Porous materials , Polyoxometalates , Adsorption , Metal–organic frameworks
Journal title
Inorganic Chemistry Communications
Serial Year
2012
Journal title
Inorganic Chemistry Communications
Record number
1319569
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