Title of article
Sandwich-type tungstoantimonates decorated by the heterometallic 3d–5p clusters
Author/Authors
Hui Duan، نويسنده , , Zhiming Zhang، نويسنده , , Xin-Bao Han، نويسنده , , Yizhen Chen، نويسنده , , Jian-Qiang Shen، نويسنده , , Weipeng Wang، نويسنده , , Xiao-Tao Zheng، نويسنده , , Huanyu Zhou، نويسنده , , En-Bo Wang، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
5
From page
90
To page
94
Abstract
A new sandwich-type tungstoantimonate (NH4)9{Cu3Sb(H2O)3(SbW9O33)2}·22H2O (1) was synthesized by reaction of the preformed large cluster [NaSb9W21O86]18 − ({Sb9W21}) and transition-metal cations. Compound 1 is a 3d–5p heterometallic cluster-containing sandwich-type tungstoantimonate, which was further connected by the H-bonding interactions into a (4, 4)-connected two dimensional (2D) supramolecular framework. Further, the introduction of the alkali metal cations into the reaction system leads to a 2D framework based on the sandwich-type tungstoantimonate by water substitution: Na(NH4)9{SbCu3Cl(SbW9O33)2}·14H2O (2).
Keywords
Electrochemistry , Heterometallic cluster , Magnetism , Sandwich , Polyoxometalate
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1319929
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