Title of article
A new polyanion with Dawson-like constitution: [H2SeW18O60]6 −
Author/Authors
Lijuan Wang، نويسنده , , Wenjuan Li، نويسنده , , Lizhou Wu، نويسنده , , Xinbo Dong، نويسنده , , Huaiming Hu، نويسنده , , Ganglin Xue، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
4
From page
122
To page
125
Abstract
A new tungstoselenite, [H2SeW18O60]6 −, was isolated under acidic medium conditions (pH = 1.7)with the monoprotonated ethylamine as cation. It represents the first example of Se-containing polyoxometalate with unusual Dawson-like construction and has fully been characterized both in solid state and in solution. The high-resolution ESI-MS confirmed that the polyanion at least contains two protons and its proton number can be up to six in solution.
Keywords
Polyoxometalates , Dawson polyanion , ESI-MS
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1320000
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