Title of article
A novel (4,6)-connected 3D metal-organic framework based on chelidamic acid: Synthesis, crystal structure and photoluminescence
Author/Authors
Wan-Feng Lin، نويسنده , , Mei-Feng Wu، نويسنده , , Shun-Chen Dai، نويسنده , , Wei-Li Dai، نويسنده , , Jianping Zou، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2013
Pages
4
From page
326
To page
329
Abstract
The aqueous solution reaction of chelidamic acid (H3CAM), succinic acid, CdCl2·2.5H2O in the air at 50 °C, along with little of ammonia added dropwise, gave rise to colorless crystals {Cd2.5(CAM)(HCAM)(H2O)7·1.5H2O}n (1), which presents an interesting (4,6)-connected 3D structure. Notably, 1 is the third homonuclear 3D framework based on H3CAM ligand, which acts as two different μ4/μ5-bridges in 1 and was abbreviated to HCAM2 − and CAM3 −, respectively, in writing molecular formula of 1. Polymer 1 exhibits strong blue photoluminescence at room temperature.
Keywords
Photoluminescence , Chelidamic Acid , (4 , 6)-connected
Journal title
Inorganic Chemistry Communications
Serial Year
2013
Journal title
Inorganic Chemistry Communications
Record number
1320047
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