Title of article
The structure of (η6-C6H5Cl)Cr(CO)2PPh3
Author/Authors
Judith L Eglin، نويسنده , , Laura T Smith، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2001
Pages
5
From page
198
To page
202
Abstract
In a synthetic route that varies from the standard procedure requiring irradiation, the (η6-C6H5Cl)Cr(CO)2PPh3 complex is obtained upon reacting (η6-C6H5Cl)Cr(CO)3 with tetrakis(triphenylphosphine)palladium(0), CuI, and trimethylsilylphenylacetylene in triethylamine. The X-ray crystal structure of the yellow–orange crystals of (η6-C6H5Cl)Cr(CO)2PPh3 allows structural comparisons to related (arene)Cr(CO)2PR3 complexes.
Keywords
Carbonyl complexes , crystal structure , Chloroarene complexes , chromium complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2001
Journal title
INORGANICA CHIMICA ACTA
Record number
1320914
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