Title of article
The isolation and structural characterization of copper(II) complexes obtained by oxidation of the 2,6-bis(dicyclohexylphosphinomethyl)pyridine and 2-(diisopropylphosphinomethyl)-1-methylimidazole ligands Review Article
Author/Authors
Huifang Lang، نويسنده , , Phillip E. Fanwick، نويسنده , , Richard A Walton، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2002
Pages
4
From page
9
To page
12
Abstract
The reactions of [Cu(NCCH3)4]BF4 with 2,6-(dicyclohexylphosphinomethyl)pyridine and 2-(diisopropylphosphinomethyl)-1-methylimidazole afford Cu(I) species that convert slowly to the Cu(II) complexes [CuCl{Cy2P(O)CH2pyCH2P(O)Cy2}(H2O)]BF4 and [Cu{MelmCH2P(O)Pri2}2](BF4)2, respectively, when their solutions are exposed to air. The structures of the Cu(II) complexes have been established by X-ray crystallography.
Keywords
crystal structures , Mixed N , O Ligands , O and O , N , Copper(II) complexes
Journal title
INORGANICA CHIMICA ACTA
Serial Year
2002
Journal title
INORGANICA CHIMICA ACTA
Record number
1321136
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